In a study recently published in Chemical Engineering Journal, researchers from Kanazawa University have chemically modified an industrial waste product, and processed it into a possible lightweight structural material. This development may increase the fuel economy of private and commercial transportation.

The researchers started with Kraft lignin, a byproduct of a common wood pulping process. Paper mills usually burn Kraft lignin to generate power, because it's difficult to use for anything except specialized purposes. Chemically processing Kraft lignin into a more useful material would improve the environmental sustainability of paper production.

"We performed a chemical modification of Kraft lignin polymer known as acetylation," says first author László Szabó. "Optimizing the extent of acetylation was critical to our research effort."

A controlled reaction was important for optimizing Kraft lignin's ability to be compatible with another polymer called polyacrylonitrile, and thus prepare quality carbon fibers creating an engineered composite. If there's too little -- or too much -- acetylation, the carbon fibers are of low quality.

"Our reaction was quite mild, producing only a rather benign side product -- acetone -- without changing the polydispersity of the Kraft lignin," explains Kenji Takahashi, co-senior author. "We thus were able to mix Kraft lignin with polyacrylonitrile to obtain a dope solution for electrospinning containing more compatible polymer segments and eventually fabricate quality carbon fibers."

The researchers' carbon fiber mats contain fine uniform fibers, without the thermal treatment lessening fiber quality. In fact, compared with unmodified Kraft lignin, by using the modified polymer the fiber mat exhibited an almost 3-fold improvement in mechanical strength.

"Our fibers' mechanical performance is attributable to the tailored graphitic structure of the materials," explains Szabó. "This outcome is owing to the improved polymer interactions leading to a more aligned polymeric network which is then subjected to the thermal treatment."

Engineered composites are common in spacecraft, cars, plastic, concrete, and many other products and technologies. When these researchers minimize the cost of preparing their new carbon fibers, perhaps vehicles of the future will be lighter, more durable, and more fuel-efficient. Given that every industry uses transportation, everyone will save money and every business will be more environmentally sustainable.

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Materials provided by Kanazawa University. Note: Content may be edited for style and length.

Journal Reference:

1. László Szabó, Romain Milotskyi, Hisai Ueda, Takayuki Tsukegi, Naoki Wada, Kenji Takahashi. Controlled acetylation of kraft lignin for tailoring polyacrylonitrile-kraft lignin interactions towards the production of quality carbon nanofibers. Chemical Engineering Journal, 2021; 405: 126640 DOI: 10.1016/j.cej.2020.126640