A major issue is that while rechargeable lithium metal anodes play a key role in how well this new wave of lithium batteries function, during battery operation they are highly susceptible to the growth of dendrites, microstructures that can lead to dangerous short-circuiting, catching on fire, and even exploding.

Researchers at Columbia Engineering report today that they have found that alkali metal additives, such as potassium ions, can prevent lithium microstructure proliferation during battery use. They used a combination of microscopy, nuclear magnetic resonance (similar to an MRI), and computational modeling to discover that adding small amounts of potassium salt to a conventional lithium battery electrolyte produces unique chemistry at the lithium/electrolyte interface. The study is published online today in Cell Reports Physical Science (and in the November 18th print edition).

"Specifically, we found that potassium ions mitigate the formation of undesirable chemical compounds that deposit on the surface of lithium metal and prevent lithium ion transport during battery charging and discharging, ultimately limiting microstructural growth," says the team's PI Lauren Marbella, assistant professor of chemical engineering.

Her team's discovery that alkali metal additives suppress the growth of non-conductive compounds on the surface of lithium metal differs from traditional electrolyte manipulation approaches, which have focused on depositing conductive polymers on the metal's surface. The work is one of the first in-depth characterizations of the surface chemistry of lithium metal using NMR, and demonstrates the power of this technique to design new electrolytes for lithium metal. Marbella's results were complemented with density functional theory (DFT) calculations performed by collaborators in the Viswanathan group in mechanical engineering at Carnegie Mellon University.

"Commercial electrolytes are a cocktail of carefully selected molecules," Marbella notes. "Using NMR and computer simulations, we can finally understand how these unique electrolyte formulations improve lithium metal battery performance at the molecular level. This insight ultimately gives researchers the tools they need to optimize electrolyte design and enable stable lithium metal batteries."

The team is now testing alkali metal additives that stop the formation of deleterious surface layers in combination with more traditional additives that encourage the growth of conductive layers on lithium metal. They are also actively using NMR to directly measure the rate of lithium transport through this layer.

Story Source:

Materials provided by Columbia University School of Engineering and Applied Science. Original written by Holly Evarts. Note: Content may be edited for style and length.

Journal Reference:

1. Richard May, Yumin Zhang, Steven R. Denny, Venkatasubramanian Viswanathan, Lauren E. Marbella. Leveraging Cation Identity to Engineer Solid Electrolyte Interphases for Rechargeable Lithium Metal Anodes. Cell Reports Physical Science, 2020 DOI: 10.1016/j.xcrp.2020.100239