Previously, scientists have proposed placing a network of sensors in the forest that could detect changes in temperature, smoke or humidity and wirelessly transmit a signal to responders. However, such a system hasn't yet seemed practical because all of the sensing components require power. Batteries would eventually go dead and need to be replaced. Thermoelectric materials, which convert temperature differences into electricity, could simultaneously detect temperature increases from fires and power themselves. However, most of these materials are solid inorganic semiconductors, which are often expensive, rigid and environmentally unfriendly. Yapei Wang and colleagues wanted to find out if ionic liquids could be used as thermoelectric materials for fire sensing. These fluids are salts in the liquid state, and two different types of ionic liquids can be connected in series to generate signals.

To make paper-based thermoelectric sensors, the researchers chose two ionic liquids that behaved differently when the temperature increased: One adsorbed to the surface of gold electrodes, while the other desorbed, producing opposite (positive or negative) voltages. They deposited each ionic liquid like an ink between two gold electrodes that were sputtered onto a piece of ordinary paper. When connected in series, the two ionic liquids produced an electric signal when a large temperature difference occurred, as would happen in a fire. In a pilot test of the new sensor, the researchers attached one to a houseplant. When they placed a flaming cotton ball close to the plant's roots, the temperature at the bottom of the sensor quickly increased, producing a voltage signal that an attached microcomputer chip wirelessly transmitted to a receiver. Upon picking up the signal, the receiver activated a sound alarm and a red light. The thermoelectric paper chips are cheap ($0.04), and the materials are eco-friendly, the researchers say.

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Materials provided by American Chemical Society. Note: Content may be edited for style and length.

Journal Reference:

1. Xun Wu, Naiwei Gao, Xiaoting Zheng, Xinglei Tao, Yonglin He, Zhiping Liu, Yapei Wang. Self-Powered and Green Ionic-Type Thermoelectric Paper Chips for Early Fire Alarming. ACS Applied Materials & Interfaces, 2020; 12 (24): 27691 DOI: 10.1021/acsami.0c04798