Method combination allows deep insights into ultrafast light-induced processes

One method for such molecular dynamic investigations makes use of so-called pump-probe measurements applying an ultrashort laser pulse to excite ("pump") a molecular system into a desired state. After an adjustable delay time, a second ("probe") laser interrogates the population of the excited state by ionizing the molecule. The energy of the emitted photoelectrons is measured and by varying the pump-probe delay time, conclusions can be drawn about the energy flow in the molecule.

Heisenberg's energy-time uncertainty principle prevents exact results

An exact description of light-induced processes on their real time scale has so far failed for some polyatomic molecules that may take different decay or fragmentation routes after excitation, depending on the choice between closely spaced energy states. As a result of Heisenberg's energy-time uncertainty principle, laser pulses of only femtosecond (10-15 seconds) time duration cannot selectively excite closely neighbouring molecular states. However, short pulses are a prerequisite for the observation of extremely fast processes.

New approach combines theory and experiment

In collaboration with researchers of the Institute of Theoretical Chemistry at the Faculty of Chemistry of the University of Vienna under the direction of Prof. Leticia González, the experimental physicists in Graz have now overcome this hurdle. By combining experiments with ultrashort laser pulses and theoretical simulations of light-induced processes, the energy flow in acetone -- a molecule that has already been well studied -- could now be observed for the first time at a key energy window between three closely related states. Even for the Vienna group, a driving force in the field of the theoretical description of molecules after light excitation, the system under investigation presented a challenge. "For these simulations, new developments in our local software package SHARC were necessary, without which the correct description of acetone dynamics would not have been possible," emphasizes González.

Synergy effects yield new insights

Both methods in themselves are widely used, but "while the energy-time-blur relation in femtosecond spectroscopy prevents precise results, real-time simulations provide deeper insights into molecular dynamics, which in turn require the experimental results to be verified," explains Koch. The combination of these two techniques now provides researchers with a deeper insight into acetone dynamics and is a further milestone in the study of light-matter interactions. The results were published in The Journal of Physical Chemistry Letters.

Story Source:

Materials provided by Graz University of Technology. Original written by Christoph Pelzl. Note: Content may be edited for style and length.

Journal Reference:

1. Pascal Heim, Sebastian Mai, Bernhard Thaler, Stefan Cesnik, Davide Avagliano, Dimitra Bella-Velidou, Wolfgang E. Ernst, Leticia González, Markus Koch. Revealing Ultrafast Population Transfer between Nearly Degenerate Electronic States. The Journal of Physical Chemistry Letters, 2020; 1443 DOI: 10.1021/acs.jpclett.9b03462