The 25-year-old lined up alongside fellow footballers and celebs from his native country as part of an event held by NBA star Nene in the city of Jundai.
The £198 million man turned out for both sides in the second half of the game against Sao Paulo, with the game finishing 11-7 to Nene's side.
But the highlight of the game was undoubtedly Neymar’s sublime finish to make it 5-1 to Nene.
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The former Barcelona man was played through on goal, bamboozling the onrushing goalie with some fancy footwork before chipping the ball into the air.
He took one touch to tee himself up before lobbing the ball over the keeper and into the far corner.
The clip has racked up more than 125,000 views since it was posted on Twitter earlier this week.
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“Neymar is better than Cristiano. Messi knows that,” wrote one viewer.
Another said: “I’m speechless. The technique.”
“That is pure filthy, go on my son,” added another.